Bulk Coordination Polymerization of Dicyclopentadiene (DCPD) by Pd Complexes Containing β-Ketoiminate or β-Diketiminate Ligands
نویسندگان
چکیده
منابع مشابه
Chemistry of nitrosyliron complexes supported by a β-diketiminate ligand.
Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)](2)CH). The dinitrosyliron complexes [Fe(NO)(2)(Ar-nacnac)] (1) and (Bu(4)N)[Fe(NO)(2)(Ar-nacnac)] (2) react with [Fe(III)(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [Fe(II)(NO)(TPP)] and the corresponding mononitrosyliron co...
متن کاملHydrogen-bond-supported dimeric boron complexes of potentially tetradentate β-diketiminate ligands.
Two dimeric boron complexes of potentially tetradentate and trianionic β-diketiminate ligands bearing phenol substituents were prepared and characterized. The synthetic routes employed were designed to circumvent the undesirable formation of β-ketimines and 2-methylbenzoxazoles observed when traditional synthetic routes toward the target β-diketiminate ligands were attempted. The title complexe...
متن کاملParamagnetic aluminium β-diketiminate.
The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.
متن کاملCopper complexes of the non-innocent β-diketiminate ligand containing phenol groups.
A new type of non-innocent β-diketiminate ligand having redox active phenol groups (LH(3), fully protonated form) has been developed, and the structure, physical properties and reactivity of the supported copper(II) complex [Cu(II)(L(3-))](-) (L(3-), fully deprotonated tri-anionic form) as well as the one-electron and two-electron oxidised complexes, [Cu(II)(L˙(2-))] and [Cu(II)(L(-))](+), have...
متن کاملPreorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand.
A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors.
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ژورنال
عنوان ژورنال: Bulletin of the Korean Chemical Society
سال: 2012
ISSN: 0253-2964
DOI: 10.5012/bkcs.2012.33.12.4131